Gong, C. et al. Discovery of intrinsic ferromagnetism in two-dimensional van der Waals crystals. Nature 546265–269 (2017). Article ADS CAS PubMed Google Scholar Chen, Y. et al. Twist-assisted fully antiferromagnetic tunnel junction at the atomic limit. Nature 6321045-1051 (2024). Article ADS CAS PubMed PubMed Central Google Scholar Naguib, M. et al. Two-dimensional nanocrystals produced by
Gong, C. et al. Discovery of intrinsic ferromagnetism in two-dimensional van der Waals crystals. Nature 546265–269 (2017).
Chen, Y. et al. Twist-assisted fully antiferromagnetic tunnel junction at the atomic limit. Nature 6321045-1051 (2024).
Naguib, M. et al. Two-dimensional nanocrystals produced by Ti exfoliation.3AlC2. Adv. Mother. 234248–4253 (2011).
VahidMohammadi, A., Rosen, J. & Gogotsi, Y. The world of two-dimensional carbides and nitrides (MXenes). Science 372eabf1581 (2021).
Zhou, J., Dahlqvist, M., Björk, J. & Rosen, J. Atomic-scale design of MXenes and their parent materials, from theoretical and experimental perspectives. Chemistry. Rev. 12313291–13322 (2023).
Li, L., Ding, Y.-S. & Zheng, Z. Lanthanide-based molecular magnetic semiconductors. Angelica. Chemistry. Int. Ed. 63e202410019 (2024).
Ding, Y.-S. et al. Atomically precise semiconductor clusters of rare earth tellurides. Nat. Synthesizer. 3655–661 (2024).
Yang, J. et al. Structural and magnetic properties of chemically ordered in-plane (Mo23R1/3)2AlC (R= Gd, Tb, Dy, Ho, Er and Y) MAX phase and enhanced Mo capacitance1.33Derived from C MXene. Coal 179104-110 (2021).
Kamysbayev, V. et al. Covalent Surface Modifications and Superconductivity of Two-Dimensional Metal Carbide MXenes. Science 369979–983 (2020).
Zhou, C. et al. Two-dimensional organic-inorganic metal carbide hybrid MXenes with amido- and imido-terminated surfaces. Nat. Chemistry. 151722-1729 (2023).
Ding, H. et al. Chemical scissors-mediated structural editing of layered transition metal carbides. Science 3791130-1135 (2023).
Kumar, H. et al. Tunable magnetism and transport properties in MXenes nitride. ACS Nano 117648–7655 (2017).
Hart, J.L. et al. Control of the electronic properties of MXenes through termination and intercalation. Community Nat. 10522 (2019).
Khazaei, M. et al. New electronic and magnetic properties of two-dimensional transition metal carbides and nitrides. Adv. Function. Mother. 232185–2192 (2013).
Hantanasirisakul, K. et al. Evidence for a magnetic transition in atomically thin Cr2Tic2tunknown MXeno. Nanoscale horizon 51557-1565 (2020).
Hassan, T. et al. Semiconductor properties of delaminated titanium nitride Ti.4north3tunknown MXene with gate-tunable electrical conductivity. ACS Nano 1823477–23488 (2024).
Stavrou, M. et al. emerging ta4do3 and mo2You2do3 MXene nanosheets for ultrafast photonics. Adv. Opt. Mother. 132403277 (2025).
Ghidiu, M., Lukatskaya, M.R., Zhao, M.-Q., Gogotsi, Y. & Barsoum, M.W. Two-dimensional titanium carbide conductive ‘clay’ with high volumetric capacitance. Nature 51678–81 (2014).
Li, Y. et al. A general Lewis acid etching route to prepare MXenes with improved electrochemical performance in nonaqueous electrolytes. Nat. Mother. 19894–899 (2020).
Wang, D. et al. Direct synthesis and chemical vapor deposition of 2D carbide-nitride MXenes. Science 3791242-1247 (2023).
Xiang, M. et al. Synthesis of Ti in the gas phase.2CCl2 enables an efficient catalyst for lithium-sulfur batteries. Innovation 5100540 (2024).
Hwu, SJ, Ziebarth, R.P., Von Winbush, S., Ford, JE & Corbett, JD Synthesis and structure of metal double-layer scandium, yttrium, and zirconium chloride carbides and nitrides, M2CL2C and M2CL2NORTH. Inorg. Chemistry. 25283–287 (1986).
Mattausch, H., Eger, R. and Simon, A. Das erste Gadoliniumcarbidfluorid: Gd2CF2. Z. Anorg. Allg. Chemistry. 597145-150 (1991).
Cockcroft, J.K., Kremer, R.K., Mattausch, H., Raju, NP and Simon, A. Structure and magnetic ordering of holmium carbide fluoride, Ho2CF2. J. Alloy. compd. 183241–251 (1992).
Druffel, DL et al. Synthesis and electronic structure of a 3D crystalline stack of MXene-type sheets. Chemistry. Mother. 319788–9796 (2019).
Simon, A., Mattausch, H. and Holzer, N. Lanthanoiden monochloride: GdCl and TbCl. Angelica. Chemistry. 88685–686 (1976).
Araujo, RE & Corbett, JD Lanthanum monochloride and lanthanum sesquichloride. Inorg. Chemistry. 203082–3086 (1981).
Song, HY et al. Van der Waals electride: towards intrinsic two-dimensional ferromagnetism of spin-polarized anionic electrons. Mother. Today Phys. 20100473 (2021).
Zhang, T. et al. Delamination of chlorine-terminated MXene produced by molten salt etching. Chemistry. Mother. 361998-2006 (2024).
Schurz, CM and Schleid, T. Cadenas de trans -connected edge [ZM4] tetrahedra (Z = N and O) in the lanthanide nitride M chlorides2NCl3 and na2METRO4ONCl9 (M = La–Nd). J. Alloy. compd. 485110-118 (2009).
Buenzli, JCG, Metabanzoulou, JP, Froidevaux, P. & Jin, L. FT-IR and fluorometric investigation of solvation of metal and rare earth ions. 9. Evidence for a change in coordination number along the lanthanide series: FT-IR investigation of solvates [Ln(NO3)3(DMSO)n] in anhydrous acetonitrile. Inorg. Chemistry. 293875–3881 (1990).
Mattausch, H., Schaloske, MC, Hoch, C., Zheng, C. and Simon, A. Seltenerdhalogenide Ln4unknown5Z. Part 1: C and/or C2 in Ln4unknown5Z. Z. Anorg. Allg. Chemistry. 634491–497 (2008).
Zheng, C., Oeckler, O., Mattausch, H. and Simon, A. La3unknown3Z – Compounds with La condensate6Z helically connected octahedra in three dimensions. Z. Anorg. Allg. Chemistry. 6272151–2162 (2001).
Hasan, MZ, Haque, MH, Ali, MA, Hossain, MM & Uddin, MM Structural, optical and photocatalytic efficiency of Ti3do2 ym2C (M = Ti, V, Cr, Nb) MXene materials synthesized using the etching technique. Advanced AIP. 15035334 (2025).
Klein, J. et al. Limitations of the Tauc chart method. Adv. Function. Mother. 332304523 (2023).
Hughes, I.D. et al. Lanthanide contraction and magnetism in the heavy rare earth elements. Nature 446650–653 (2007).
Huang, B. et al. Layer-dependent ferromagnetism in a van der Waals crystal up to the monolayer limit. Nature 546270–273 (2017).
Liang, J., Cui, Q. and Yang, H. Dzyaloshinskii-Moriya interaction of electrically switchable Rashba-type and skyrmion in two-dimensional magnetoelectric multiferroics. Physics. Rev. B 102220409 (2020).
Sandratskii, LM Symmetry analysis of electronic states for crystals with spiral magnetic order. I. General properties. J. Physics. Counts. Affair 38565 (1991).
Bader, R.F.W. Atoms in molecules: a quantum theory(Oxford University Press, 1990).
Dollase, WA Correction of intensities for preferred orientation in powder diffractometry: application of the March model. J. Apply. Crystallogr. 19267–272 (1986).
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