Zhang, X. et al. Regioselective hydroformylation of propene catalysed by rhodium-zeolite. Nature 629, 597–602 (2024). Article ADS CAS PubMed Google Scholar Yu, Z. et al. Suppressing metal leaching and sintering in hydroformylation reaction by modulating the coordination of Rh single atoms with reactants. J. Am. Chem. Soc. 146, 11955–11967 (2024). Article ADS CAS PubMed Google
Zhang, X. et al. Regioselective hydroformylation of propene catalysed by rhodium-zeolite. Nature 629, 597–602 (2024).
Google Scholar
Yu, Z. et al. Suppressing metal leaching and sintering in hydroformylation reaction by modulating the coordination of Rh single atoms with reactants. J. Am. Chem. Soc. 146, 11955–11967 (2024).
Google Scholar
Dou, X. et al. Regioselective hydroformylation with subnanometre Rh clusters in MFI zeolite. Nat. Catal. 7, 666–677 (2024).
Google Scholar
Franke, R., Selent, D. & Börner, A. Applied hydroformylation. Chem. Rev. 112, 5675–5732 (2012).
Google Scholar
Ro, I. et al. Bifunctional hydroformylation on heterogeneous Rh-WOx pair site catalysts. Nature 609, 287–292 (2022).
Google Scholar
Yang, C. et al. Increased productivity in ethylene carbonylation by zeolite-supported molybdenum carbonyls. J. Catal. 338, 313–320 (2016).
Google Scholar
Yang, C., Kilos, B. A., Barton, D. G., Weitz, E. & Notestein, J. M. The role of iodide promoters and the mechanism of ethylene carbonylation catalyzed by molybdenum hexacarbonyl. J. Catal. 319, 211–219 (2014).
Google Scholar
Fan, B. et al. Elucidation of hemilabile-coordination-induced tunable regioselectivity in single-site Rh-catalyzed heterogeneous hydroformylation. Nat. Commun. 15, 6967 (2024).
Google Scholar
Yang, J. et al. Direct synthesis of adipic acid esters via palladium-catalyzed carbonylation of 1,3-dienes. Science 366, 1514–1517 (2019).
Google Scholar
Wang, X. et al. Carbonylation of ethane with carbon monoxide over Zn-modified ZSM-5 zeolites studied by in situ solid-state NMR spectroscopy. J. Catal. 345, 228–235 (2017).
Google Scholar
Zoeller, J. R., Blakely, E. M., Moncier, R. M. & Dickson, T. J. Molybdenum catalyzed carbonylation of ethylene to propionic acid and anhydride. Catal. Today 36, 227–241 (1997).
Google Scholar
Peng, J., Geng, H. & Wu, X. The chemistry of CO: carbonylation. Chem 5, 526–552 (2019).
Google Scholar
Koch, H. & Möller, K. E. Process for producing carboxylic acids from olefins, carbon monoxide and water. US patent 3,061,621 (1962).
Li, T., Tsumori, N., Souma, Y. & Xu, Q. Highly active and stable performance of catalytic vapor phase Koch-type carbonylation of tert-butyl alcohol over H-zeolites. Chem. Commun. 21, 2070–2071 (2003).
Google Scholar
Luzgin, M. V., Romannikov, V. N., Stepanov, A. G. & Zamaraev, K. I. Interaction of olefins with carbon monoxide on zeolite H-ZSM-5. NMR observation of the Friedel−Crafts acylation of alkenes at ambient temperature. J. Am. Chem. Soc. 118, 10890–10891 (1996).
Google Scholar
Fujimoto, K., Shikada, T., Omata, K. & Tominaga, H.-o. Vapor phase carbonylation of methanol with solid acid catalysts. Chem. Lett. 13, 2047–2050 (1984).
Google Scholar
Stepanov, A. G., Luzgin, M. V., Romannikov, V. N., Sidelnikov, V. N. & Zamaraev, K. I. Formation of carboxylic acids from alcohols and olefins in zeolite H-ZSM-5 under mild conditions via trapping of alkyl carbenium ions with carbon monoxide: an in situ 13C solid state NMR study. J. Catal. 164, 411–421 (1996).
Google Scholar
Stepanov, A. G., Luzgin, M. V., Romannikov, V. N. & Zamaraev, K. I. NMR observation of the Koch reaction in zeolite H-ZSM-5 under mild conditions. J. Am. Chem. Soc. 117, 3615–3616 (1995).
Google Scholar
Celik, F. E., Kim, T., Mlinar, A. N. & Bell, A. T. An investigation into the mechanism and kinetics of dimethoxymethane carbonylation over FAU and MFI zeolites. J. Catal. 274, 150–162 (2010).
Google Scholar
Celik, F. E., Kim, T. J. & Bell, A. T. Vapor-phase carbonylation of dimethoxymethane over H-Faujasite. Angew. Chem. Int. Ed. 48, 4813–4815 (2009).
Google Scholar
Boronat, M., Martínez-Sánchez, C., Law, D. & Corma, A. Enzyme-like specificity in zeolites: a unique site position in mordenite for selective carbonylation of methanol and dimethyl ether with CO. J. Am. Chem. Soc. 130, 16316–16323 (2008).
Google Scholar
Bhan, A., Allian, A. D., Sunley, G. J., Law, D. J. & Iglesia, E. Specificity of sites within eight-membered ring zeolite channels for carbonylation of methyls to acetyls. J. Am. Chem. Soc. 129, 4919–4924 (2007).
Google Scholar
Cheung, P., Bhan, A., Sunley, G. J. & Iglesia, E. Selective carbonylation of dimethyl ether to methyl acetate catalyzed by acidic zeolites. Angew. Chem. Int. Ed. 45, 1617–1620 (2006).
Google Scholar
Baerlocher, Ch., Meier, W. M. & Olson, D. H. Atlas of Zeolite Framework Types (Elsevier, 2001).
Pinar, A. B. et al. Pinpointing and quantifying the aluminum distribution in zeolite catalysts using anomalous scattering at the Al absorption edge. J. Am. Chem. Soc. 143, 17926–17930 (2021).
Google Scholar
Dedecek, J. et al. Complex analysis of the aluminum siting in the framework of silicon-rich zeolites. A case study on ferrierites. J. Phys. Chem. C 115, 11056–11064 (2011).
Google Scholar
Gong, X. et al. First-generation organic reaction intermediates in zeolite chemistry and catalysis. Chem. Rev. 122, 14275–14345 (2022).
Google Scholar
Tamura, M., Shimizu, K.-i. & Satsuma, A. Comprehensive IR study on acid/base properties of metal oxides. Appl. Catal. A Gen. 433–434, 135–145 (2012).
Google Scholar
Wichterlová, B., Tvarůžková, Z., Sobalík, Z. & Sar, P. Determination and properties of acid sites in H-ferrierite: a comparison of ferrierite and MFI structures. Microporous Mesoporous Mater. 24, 223–233 (1998).
Google Scholar
Lakiss, L. et al. Probing the Brønsted acidity of the external surface of Faujasite-type zeolites. ChemPhysChem 21, 1873–1881 (2020).
Google Scholar
Lesthaeghe, D., De Sterck, B., Van Speybroeck, V., Marin, G. B. & Waroquier, M. Zeolite shape-selectivity in the gem-methylation of aromatic hydrocarbons. Angew. Chem. Int. Ed. 46, 1311–1314 (2007).
Google Scholar
Chai, J.-D. & Head-Gordon, M. Long-range corrected hybrid density functionals with damped atom–atom dispersion corrections. Phys. Chem. Chem. Phys. 10, 6615–6620 (2008).
Google Scholar
Frisch, M. J. et al. Gaussian 09, Revision B.01 (Gaussian, Inc., 2010).
Check back often for more exciting news!
