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Conjugation-regulated self-assembled molecules for tandem solar cells – Nature

Conjugation-regulated self-assembled molecules for tandem solar cells – Nature

Jia, L. et al. Efficient perovskite/silicon tandem with asymmetric self-assembly molecule. Nature 644, 912–919 https://doi.org/10.1038/s41586-025-09333-z (2025). Article  ADS  CAS  PubMed  Google Scholar  Wu, W. et al. Stable and uniform self-assembled organic diradical molecules for perovskite photovoltaics. Science 389, 195–199 https://doi.org/10.1126/science.adv4551 (2025). Article  ADS  CAS  PubMed  Google Scholar  Green, M. A. et al. Solar cell efficiency

  • Jia, L. et al. Efficient perovskite/silicon tandem with asymmetric self-assembly molecule. Nature 644, 912–919 https://doi.org/10.1038/s41586-025-09333-z (2025).

    Article 
    ADS 
    CAS 
    PubMed 

    Google Scholar 

  • Wu, W. et al. Stable and uniform self-assembled organic diradical molecules for perovskite photovoltaics. Science 389, 195–199 https://doi.org/10.1126/science.adv4551 (2025).

    Article 
    ADS 
    CAS 
    PubMed 

    Google Scholar 

  • Green, M. A. et al. Solar cell efficiency tables (version 67). Prog. Photovoltaics Res. Appl. 34, 482–496 https://doi.org/10.1002/pip.70068 (2026).

    Article 

    Google Scholar 

  • Liu, J. et al. Perovskite/silicon tandem solar cells with bilayer interface passivation. Nature 635, 596–603 https://doi.org/10.1038/s41586-024-07997-7 (2024).

    Article 
    ADS 
    CAS 
    PubMed 

    Google Scholar 

  • Ugur, E. et al. Enhanced cation interaction in perovskites for efficient tandem solar cells with silicon. Science 385, 533–538 https://doi.org/10.1126/science.adp1621 (2024).

    Article 
    ADS 
    CAS 
    PubMed 

    Google Scholar 

  • Aydin, E. et al. Enhanced optoelectronic coupling for perovskite/silicon tandem solar cells. Nature 623, 732–738 https://doi.org/10.1038/s41586-023-06667-4 (2023).

    Article 
    ADS 
    CAS 
    PubMed 

    Google Scholar 

  • Mariotti, S. et al. Interface engineering for high-performance, triple-halide perovskite–silicon tandem solar cells. Science 381, 63–69 https://doi.org/10.1126/science.adf5872 (2023).

    Article 
    ADS 
    CAS 
    PubMed 

    Google Scholar 

  • Chin, X. Y. et al. Interface passivation for 31.25%-efficient perovskite/silicon tandem solar cells. Science 381, 59–63 https://doi.org/10.1126/science.adg0091 (2023).

    Article 
    ADS 
    CAS 
    PubMed 

    Google Scholar 

  • Li, N. et al. Optimal perovskite vapor partitioning on textured silicon for high-stability tandem solar cells. Science 390, eadz3698 https://doi.org/10.1126/science.adz3698 (2026).

    Article 
    CAS 

    Google Scholar 

  • Chen, Y. et al. Nuclei engineering for even halide distribution in stable perovskite/silicon tandem solar cells. Science 385, 554–560 https://doi.org/10.1126/science.ado9104 (2024).

    Article 
    ADS 
    CAS 
    PubMed 

    Google Scholar 

  • Fei, C. et al. Limiting phosphonic acid interlayer–perovskite reactivity to stabilize perovskite solar modules. Science 391, eadz7969 https://doi.org/10.1126/science.adz7969 (2026).

    Article 
    CAS 
    PubMed 

    Google Scholar 

  • Liu, S. et al. Buried interface molecular hybrid for inverted perovskite solar cells. Nature 632, 536–542 https://doi.org/10.1038/s41586-024-07723-3 (2024).

    Article 
    ADS 
    CAS 
    PubMed 

    Google Scholar 

  • Liang, Y. et al. A matrix-confined molecular layer for perovskite photovoltaic modules. Nature 648, 91–96 https://doi.org/10.1038/s41586-025-09785-3 (2025).

    Article 
    ADS 
    CAS 
    PubMed 

    Google Scholar 

  • Jiang, W. et al. Toughened self-assembled monolayers for durable perovskite solar cells. Nature 646, 95–101 https://doi.org/10.1038/s41586-025-09509-7 (2025).

    Article 
    ADS 
    CAS 
    PubMed 

    Google Scholar 

  • Luo, C. et al. Engineering bonding sites enables uniform and robust self-assembled monolayer for stable perovskite solar cells. Nat. Mater. 24, 1265–1272 https://doi.org/10.1038/s41563-025-02275-x (2025).

    Article 
    CAS 
    PubMed 

    Google Scholar 

  • Fei, C. et al. Strong-bonding hole-transport layers reduce ultraviolet degradation of perovskite solar cells. Science 384, 1126–1134 https://doi.org/10.1126/science.adi4531 (2024).

    Article 
    ADS 
    CAS 
    PubMed 

    Google Scholar 

  • Guo, C. et al. Bifacially reinforced self-assembled monolayer interfaces for minimized recombination loss and enhanced stability in perovskite/silicon tandem solar cells. Adv. Mater. 37, 2504520 https://doi.org/10.1002/adma.202504520 (2025).

    Article 
    CAS 

    Google Scholar 

  • Feng, Y. et al. Homogenized self-assembled molecules for inverted perovskite solar cells. Angew. Chem. Int. Ed. 64, e202505876 https://doi.org/10.1002/anie.202505876 (2025).

    Article 
    CAS 

    Google Scholar 

  • He, R. et al. Improving interface quality for 1-cm2 all-perovskite tandem solar cells. Nature 618, 80–86 https://doi.org/10.1038/s41586-023-05992-y (2023).

    Article 
    ADS 
    CAS 
    PubMed 

    Google Scholar 

  • Zhou, J. et al. Molecular contacts with an orthogonal π-skeleton induce amorphization to enhance perovskite solar cell performance. Nat. Chem. 17, 564–570 https://doi.org/10.1038/s41557-025-01732-z (2025).

    Article 
    CAS 
    PubMed 

    Google Scholar 

  • Zhao, K. et al. peri-Fused polyaromatic molecular contacts for perovskite solar cells. Nature 632, 301–306 https://doi.org/10.1038/s41586-024-07712-6 (2024).

    Article 
    ADS 
    CAS 
    PubMed 

    Google Scholar 

  • Wang, X. et al. Regulating phase homogeneity by self-assembled molecules for enhanced efficiency and stability of inverted perovskite solar cells. Nat. Photonics 18, 1269–1275 https://doi.org/10.1038/s41566-024-01531-x (2024).

    Article 
    ADS 
    CAS 

    Google Scholar 

  • Park, S. M. et al. Low-loss contacts on textured substrates for inverted perovskite solar cells. Nature 624, 289–294 https://doi.org/10.1038/s41586-023-06745-7 (2023).

    Article 
    ADS 
    CAS 
    PubMed 

    Google Scholar 

  • Geng, C. et al. Two-terminal perovskite/Cu(In,Ga)Se2 tandems with conformal coatings based on commercial bottom cells with >26% efficiency. Energy Environ. Sci. 18, 8907–8917 https://doi.org/10.1039/D5EE03339J (2025).

    Article 
    CAS 

    Google Scholar 

  • Zhang, Y. et al. A π-conjugated molecular bridge strategy for constructing efficient hole transport pathways in inverted perovskite solar cells. Angew. Chem. Int. Ed. 64, e202514640 https://doi.org/10.1002/anie.202514640 (2025).

    Article 
    CAS 

    Google Scholar 

  • Du, J. et al. Face-on oriented self-assembled molecules with enhanced π–π stacking for highly efficient inverted perovskite solar cells on rough FTO substrates. Energy Environ. Sci. 18, 3196–3210 https://doi.org/10.1039/D4EE05849F (2025).

    Article 
    CAS 

    Google Scholar 

  • Zhu, P. et al. Symmetry-driven engineering of long-range-ordered π–π stacking molecules for high-efficiency perovskite photovoltaics. Nat. Synth. 5, 64–73 https://doi.org/10.1038/s44160-025-00896-3 (2026).

    Article 
    CAS 

    Google Scholar 

  • Chang, Y. et al. Highly oriented and ordered co-assembly monolayers for inverted perovskite solar cells. Angew. Chem. Int. Ed. 64, e202418883 https://doi.org/10.1002/anie.202418883 (2025).

    Article 
    CAS 

    Google Scholar 

  • Zhang, D. et al. Perovskite crystallization control via an engineered self-assembled monolayer in perovskite–silicon tandem solar cells. Nat. Photonics 20, 40–48 https://doi.org/10.1038/s41566-025-01778-y (2026).

    Article 
    ADS 
    CAS 

    Google Scholar 

  • Xiong, S. et al. Disentangling perovskite surface work functions and electron extraction energy offsets to drive high photovoltaic efficiency. Sci. Bull. 70, 1968–1975 https://doi.org/10.1016/j.scib.2025.03.034 (2025).

    Article 

    Google Scholar 

  • Gutierrez-Partida, E. et al. Toward understanding the built-in field in perovskite solar cells through layer-by-layer surface photovoltage measurements. ACS Appl. Mater. Interfaces 17, 11176–11186 https://doi.org/10.1021/acsami.4c14194 (2025).

    Article 
    CAS 
    PubMed 
    PubMed Central 

    Google Scholar 

  • Warby, J. et al. Mismatch of quasi-Fermi level splitting and Voc in perovskite solar cells. Adv. Energy Mater. 13, 2303135 https://doi.org/10.1002/aenm.202303135 (2023).

    Article 
    CAS 

    Google Scholar 

  • Liu, J. et al. Efficient and stable perovskite-silicon tandem solar cells through contact displacement by MgFx. Science 377, 302–306 https://doi.org/10.1126/science.abn8910 (2022).

    Article 
    ADS 
    CAS 
    PubMed 

    Google Scholar 

  • Xu, F. et al. Stabilized perovskite phases enabling efficient perovskite/perovskite/silicon triple-junction solar cells. Nat. Mater. 25, 259–266 https://doi.org/10.1038/s41563-025-02367-8 (2026).

    Article 
    CAS 
    PubMed 

    Google Scholar 

  • Er-Raji, O. et al. Electron accumulation across the perovskite layer enhances tandem solar cells with textured silicon. Science 390, eadx1745 https://doi.org/10.1126/science.adx1745 (2025).

    Article 
    CAS 
    PubMed 

    Google Scholar 

  • Ye, F. et al. Minimizing recombination at the perovskite/C60 interface through a volatile highly dense molecular interlayer. ACS Energy Lett. 10, 2942–2951 https://doi.org/10.1021/acsenergylett.5c00615 (2025).

    Article 
    CAS 

    Google Scholar 

  • Thiesbrummel, J. et al. Ion-induced field screening as a dominant factor in perovskite solar cell operational stability. Nat. Energy 9, 664–676 https://doi.org/10.1038/s41560-024-01487-w (2024).

    Article 
    ADS 
    CAS 

    Google Scholar 

  • Thiesbrummel, J. et al. Universal current losses in perovskite solar cells due to mobile ions. Adv. Energy Mater. 11, 2101447 https://doi.org/10.1002/aenm.202101447 (2021).

    Article 
    CAS 

    Google Scholar 

  • Kalasariya, N. et al. How halide segregation governs the ion density evolution and ionic performance losses: from degradation to recovery. Adv. Energy Mater. 16, e03866 https://doi.org/10.1002/aenm.202503866 (2026).

    Article 
    CAS 

    Google Scholar 

  • Diethelm, M. et al. Probing ionic conductivity and electric field screening in perovskite solar cells: a novel exploration through ion drift currents. Energy Environ. Sci. 18, 1385–1397 https://doi.org/10.1039/D4EE02494J (2025).

    Article 
    PubMed 

    Google Scholar 

  • Siefer, G., Baur, C. & Bett, A. W. External quantum efficiency measurements of germanium bottom subcells: measurement artifacts and correction procedures. In Proc. 2010 35th IEEE Photovoltaic Specialists Conference 704–707 https://doi.org/10.1109/PVSC.2010.5616919 (IEEE, 2010).

  • Steiner, M. A. et al. Measuring IV curves and subcell photocurrents in the presence of luminescent coupling. IEEE J. Photovolt. 3, 879–887 https://doi.org/10.1109/JPHOTOV.2012.2228298 (2013).

    Article 

    Google Scholar 

  • Lu, T. & Chen, F. Multiwfn: a multifunctional wavefunction analyzer. J. Comput. Chem. 33, 580–592 https://doi.org/10.1002/jcc.22885 (2012).

    Article 
    ADS 
    CAS 
    PubMed 

    Google Scholar 

  • Neese, F. Software update: the ORCA program system—version 5.0. Wiley Interdiscip. Rev. Comput. Mol. Sci. 12, e1606 https://doi.org/10.1002/wcms.1606 (2022).

    Article 

    Google Scholar 

  • Kresse, G. & Hafner, J. Ab initio molecular dynamics for liquid metals. Phys. Rev. B 47, 558–561 https://doi.org/10.1103/PhysRevB.47.558 (1993).

    Article 
    ADS 
    CAS 

    Google Scholar 

  • Kresse, G. & Hafner, J. Ab initio molecular-dynamics simulation of the liquid-metal–amorphous-semiconductor transition in germanium. Phys. Rev. B 49, 14251–14269 https://doi.org/10.1103/PhysRevB.49.14251 (1994).

    Article 
    ADS 
    CAS 

    Google Scholar 

  • Thompson, A. P. et al. LAMMPS—a flexible simulation tool for particle-based materials modeling at the atomic, meso, and continuum scales. Comput. Phys. Commun. 271, 108171 https://doi.org/10.1016/j.cpc.2021.108171 (2022).

    Article 
    CAS 

    Google Scholar 

  • Dodda, L. S., Cabeza de Vaca, I., Tirado-Rives, J. & Jorgensen, W. L. LigParGen web server: an automatic OPLS-AA parameter generator for organic ligands. Nucleic Acids Res. 45, W331–W336 https://doi.org/10.1093/nar/gkx312 (2017).

    Article 
    CAS 
    PubMed 
    PubMed Central 

    Google Scholar 

  • Meltzer, C. et al. Indentation and self-healing mechanisms of a self-assembled monolayer—a combined experimental and modeling study. J. Am. Chem. Soc. 136, 10718–10727 https://doi.org/10.1021/ja5048076 (2014).

    Article 
    ADS 
    CAS 
    PubMed 

    Google Scholar 

  • Li, D. et al. Co-adsorbed self-assembled monolayer enables high-performance perovskite and organic solar cells. Nat. Commun. 15, 7605 https://doi.org/10.1038/s41467-024-51760-5 (2024).

    Article 
    ADS 
    CAS 
    PubMed 
    PubMed Central 

    Google Scholar 

  • Lorenzoni, A., Mosca Conte, A., Pecchia, A. & Mercuri, F. Nanoscale morphology and electronic coupling at the interface between indium tin oxide and organic molecular materials. Nanoscale 10, 9376–9385 https://doi.org/10.1039/c8nr02341g (2018).

    Article 
    CAS 
    PubMed 

    Google Scholar 

  • Rappe, A. K., Casewit, C. J., Colwell, K. S., Goddard, W. A. III & Skiff, W. M. UFF, a full periodic table force field for molecular mechanics and molecular dynamics simulations. J. Am. Chem. Soc. 114, 10024–10035 https://doi.org/10.1021/ja00051a040 (1992).

    Article 
    ADS 
    CAS 

    Google Scholar 

  • Martínez, L., Andrade, R., Birgin, E. G. & Martínez, J. M. PACKMOL: a package for building initial configurations for molecular dynamics simulations. J. Comput. Chem. 30, 2157–2164 https://doi.org/10.1002/jcc.21224 (2009).

    Article 
    ADS 
    CAS 
    PubMed 

    Google Scholar 

  • Stukowski, A. Visualization and analysis of atomistic simulation data with OVITO–the Open Visualization Tool. Model. Simul. Mater. Sci. Eng. 18, 015012 https://doi.org/10.1088/0965-0393/18/1/015012 (2010).

    Article 
    ADS 

    Google Scholar 

  • Knight, A. J. & Herz, L. M. Preventing phase segregation in mixed-halide perovskites: a perspective. Energy Environ. Sci. 13, 2024–2046 https://doi.org/10.1039/d0ee00788a (2020).

    Article 
    CAS 

    Google Scholar 

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